yep, probably the benzenoids, naphthalenes, anthracenes and other cyclic really nasty carcinogenic and densest hydrocarbons.
the lighter heptanes pentanes etc etc are probably stuck in the middle or trying to make their way up. they are much much less toxic.
for instance, methane, the lightest of the bunch is completely non toxic. though you can still asphyxiate on it in high enough concentrations.
I think somebody did a calculation that the entire 100,000,000 barrel??? spill if it covered an area the size of WA state it would only be 1mm thick???
I haven't bothered to do the actual calc to verify this